Gas Sorption, Diffusion, and Permeation in Nafion

On gas permeation in PDMS

A theoretical model of gas permeation in polydimethylsiloxane (PDMS) is conducted for two prior works involving MEMS sensors and actuators. The issue for modeling a sensor is about using PDMS slabs to replace Pyrex glass as the packaging substrate for bulk-micromachined pressure sensors. The leakage pressure due to gas permeation in PDMS reveals the time-varying behavior of exponential decay. T...

Permeation and self-diffusion in smectics A

2014 Recent R.M.N. and quasi-elastic neutron scattering experiments on smectics A have given comparable values for the self-diffusion coefficients D~ (diffusion normal to the layers) and D~, in spite of the possible occurence of a permeation process which would lead to much lower values for D ~. It is shown that there is no permeation in a self-diffusion experiment, and therefore that the Einst...

Vapour sorption and permeation properties of poly ( dimethylsiloxane ) films *

Sorption and permeation of several organic vapours in poly(dimethylsiloxane) were investigated. Solubility and permeability coefficients measured show a strong dependence of the applied vapour activity typical for these systems, contrary to the behaviour of permanent gases. However, as irregularities in the series of chloromethanes show, highest sorption does not necessarily lead to the highest...

Study on the Adsorption, Diffusion and Permeation Selectivity of Shale Gas in Organics

As kerogen is the main organic component in shale, the adsorption capacity, diffusion and permeability of the gas in kerogen plays an important role in shale gas production. Based on the molecular model of type II kerogen, an organic nanoporous structure was established. The Grand Canonical Monte Carlo (GCMC) and Molecular Dynamics (MD) methods were used to study the adsorption and diffusion ca...

Simulstion of Gas Diffusion in Capillaries and Porous Solids